By Ilan Brat 

U.S. fertilizer maker CF Industries Holdings Inc. agreed to buy parts of a Dutch competitor for about $8 billion and shift its headquarters to the U.K., creating a global nitrogen-fertilizer powerhouse with a significantly lower tax bill.

The so-called tax inversion deal would combine CF with OCI NV's European, North American and global distribution operations. The transaction would create the world's largest publicly traded nitrogen fertilizer company and lower CF's overall tax rate to 20% from the current 34%, CF said.

Under the agreement, the companies plan to form a holding company domiciled in the U.K. in which shareholders of Deerfield, Ill.-based CF would own a 72.3% stake. The remainder would be held by shareholders in OCI. The deal is valued at $8 billion based on CF's current share price and the assumption of $2 billion in debt.

Tony Will, chief executive of CF, said on a conference call with investors Thursday that it pursued the purchase because of expansion prospects, not to lower its tax rate. "This is not a tax-driven deal," he said. "I would view this as a combination with great industrial logic."

CF shares jumped about 3.8% to $63.97 in midmorning trading.

The CF-OCI deal is the latest from chemical companies that have announced more than $50 billion of tie-ups in the past year. It also marks the latest in a partial revival of controversial tax-inversion deals. A wave of companies struck such deals last year before the U.S. Treasury put in place rules aimed at curbing them, in an effort to keep tax revenue from shifting overseas, but the moves didn't completely quash the deals.

CF said North America imports about 40% of its nitrogen fertilizer, which is heavily consumed by corn and other crops, and CF's plants in the U.S. and Canada are at capacity trying to fill current demand. The two companies are building four new plants that would boost their production capacity 65% in the next two years. At the same time, CF sees new opportunities through OCI to grow exports to Europe and Brazil. Logistics, tax and other savings will eventually lower costs by about $500 million annually, CF officials said Thursday.

CF, which has about $5 billion in annual sales, last year held merger talks with Norway's Yara International ASA in an attempt to create the world's largest nitrogen-fertilizer company. The talks fell apart as the two sides failed to agree on terms.

A steep decrease in U.S. natural gas prices in the past decade spurred by a huge increase in U.S. shale-gas production has benefited CF. Natural gas is a key raw material for making nitrogen fertilizers. Its price decline has allowed CF to buy back $5.4 billion worth of its shares since 2011.

Maarten van Tartwijk contributed to this article.

Write to Ilan Brat at ilan.brat@wsj.com

Write to Maarten van Tartwijk at maarten.vantartwijk@wsj.com

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