By P.R. Venkat 

Singapore state investment firm Temasek Holdings Pte. Ltd. is in advanced talks to buy a stake in Li Ka-shing's A.S. Watson & Co. that could be valued at billions of dollars, people with knowledge of the deal said Friday, which could put paid to the Asian tycoon's plans for a dual listing in Hong Kong and London.

While bankers continue to work on a dual summer listing of up to US$6 billion, Temasek's move is a big step for the retailer, which Mr. Li himself said in recent weeks was set to go public. Yet, buying into Watson, which owns drugstores in Hong Kong, Singapore and the U.K., would fit into Temasek's strategy of having exposure to companies benefiting from the consumer boom in emerging as well as developed markets.

Temasek owns almost a fifth of London-based emerging-markets bank Standard Chartered PLC as well as stakes in Spanish oil-and-gas company Repsol SA.

It wasn't immediately clear exactly how much Temasek would invest in Mr. Li's retail flagship, though the people familiar with the matter said it was "strategic" and would be one of the firm's biggest overseas investments.

In October, Mr. Li's Hutchison Whampoa Ltd. said in a filing that it planned a strategic review of its retail interests, after scrapping an up to US$4 billion sale of Watson's supermarket business, ParknShop, because offers didn't meet its expectations. It noted then it wouldn't "consider giving up control" of the business.

The 85-year-old Mr. Li, Asia's richest man, said last month a listing of Watson in Hong Kong and a second venue was in the works. Bankers have been working on listing the retailer in both Hong Kong and London, with a potential Singapore listing further down the road an option, people familiar with the matter said more recently.

It wasn't clear what would happen to immediate IPO plans with such a massive investment of billions of dollars from Temasek, as guidance from the Hong Kong Stock Exchange forbids major investments and most shareholding changes under 28 days before the listing hopeful applies for approval. Watson, which apart from drugstores owns electrical- appliance retailers and supermarkets, was looking into applying for Hong Kong listing approval by the end of March, other people said earlier.

If the deal is struck, an announcement could be made soon, one of the people said.

Mr. Li has been raising money by listing his portfolio companies for past several years. In January he raised $3.11 billion through an IPO of his Hong Kong electricity assets. In 2011, in a Singapore listing of his port assets he raised US$5.5 billion. The billionaire has been buying as well--he has picked up utility assets in Europe such as the U.K.'s electricity-distribution networks.

Mr. Li ended the attempted sale of ParknShop to buyers that included Australia's Woolworths Ltd. after failing to get the $3 billion to $4 billion he sought for the business.

For its part, Temasek has been looking to bulk up its presence in sectors like consumer, energy and technology. Last week, a Temasek-led consortium unveiled a US$2 billion offer to buy shares that it doesn't already own in Singapore-listed commodity trader Olam International Ltd. Early last year, the investment company paid a few hundred million dollars for a stake in Indonesia's PT Matahari Putra Prima when private-equity firm CVC Capital Partners sold shares to raise US$1.3 billion.

Established in 1974, Temasek manages a portfolio of $170 billion and owns controlling stakes in some of Singapore's biggest corporations, including Singapore Airlines Ltd. and SingTel, Southeast Asia's largest telecommunications company. It also has significant holdings in banks, including 18% of Standard Chartered and 29% of Singapore's DBS Group Holdings Ltd. Some of the biggest investments the company made were during the financial crisis of 2008 during which it invested billions of dollars to buy help out Western banks such as Barclays PLC and Merrill Lynch & Co., now Bank of America Merrill Lynch.

Watson, which has been valued by analysts at more than US$20 billion, is planning to open more than 1,200 new stores globally this year. As of the end of last year, Watson had around 10,500 stores in 25 markets across Europe, Greater China and Southeast Asia. Last year, Watson reported an 11% increase in earnings before interest expenses and other finance costs, tax, depreciation and amortization. The total rose to 14.2 billion Hong Kong dollars (US$1.8 billion), driven by new store openings.

Prudence Ho and Yvonne Lee contributed to this article.

Write to P.R. Venkat at venkat.pr@wsj.com

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