By Liam Moloney 

ROME--Italy's new premier, Matteo Renzi, Monday named a slate of bosses at Italy's biggest state-controlled groups, in one of the first tests of his promise to deliver economic change.

Mr. Renzi, who swept to power in February, announced the names of new chief executives at Eni SpA and Enel SpA, among the country's biggest companies, as well as key groups such as defense group Finmeccanica SpA and Italy's post office, which is scheduled to be privatized later this year.

The nomination process at Italy's state companies has always been the subject of intense debate because of the outsize role still played by the groups, which together make up one-third of the Italian stock market. Mr. Renzi, who has shot to prominence on his outsider status, has taken aim at the political horse trading that has long conditioned the choice of the leaders of state companies.

In a mix of continuity and change, the Renzi government announced that it would replace Eni Chief Executive Paolo Scaroni with his No. 2 executive, Claudio Descalzi, while Enel CEO Fulvio Conti would be replaced by Francesco Starace, another longtime executive at the electricity utility.

Rome also named women to replace chairmen at the two companies as part of an effort in the country to include more women on boards of companies. The government is the biggest shareholder of Eni and Enel, with stakes of 30% and 31%, respectively, giving it the power to effectively pick the board members.

With a raft of executives reaching the end of their three-year terms, Mr. Renzi, 39 years old, pledged to select new corporate leaders based on transparency and merit. The companies' shareholders are slated to approve the nominations next month.

"Here is a team of professionals of great quality...who will surely work to reach ambitious strategic targets of companies that represent fundamental assets for the country," Mr. Renzi said after the nominations.

Mr. Scaroni, 67, had been fighting for a fourth three-year term, but his chances appeared to wane at the end of March when he received a suspended three-year jail term for environmental violations occurring during his leadership of Enel about a decade ago. Mr. Scaroni said he will appeal.

Mr. Scaroni had helped transform Eni into a pure oil and gas company by shedding its regulated natural gas business and pouring money into exploration. The investment paid off with the company's first of a series of large gas discoveries from 2012 in offshore Mozambique--its largest find ever--as well as the Republic of Congo and new Asian markets such as Pakistan.

But at the same time, Mr. Scaroni's bet on the massive Kashagan project in Kazakhstan has run into huge cost overruns and years of delay. The company has also been bogged down by unrest in Libya, its single biggest producing country.

As new CEO, Mr. Descalzi, a 59-year-old executive who joined Eni in 1981 before rising to the head of exploration and production in 2008, must now push ahead with the development of Eni's big discoveries. He must also manage Eni's close ties to gas company OAO Gazprom amid growing tensions between Russia and Europe and the U.S. over the Ukraine crisis.

"Our achievements while he was COO of the E&P division speak for themselves, and I strongly endorse his nomination," said Mr. Scaroni in an emailed statement to The Wall Street Journal.

The government also named Emma Marcegaglia as Eni's new chairwoman, replacing Giuseppe Recchi, a former General Electric Co. executive who is expected to become chairman of Telecom Italia SpA.

At Enel, the government tapped Francesco Starace, 58, as CEO, turning to another company insider who heads renewables company Enel Green Power SpA. Mr. Starace replace Fulvio Conti, 66, who, like Mr. Scaroni, had also hoped to be given a fourth three-year term.

Mr. Conti transformed Enel from an almost pure Italian player to an international one thanks to its acquisition of Spain's Endesa SA in 2007, which gave it a strong presence in Latin America. But the deal left Enel saddled with debt. Mr. Starace must now strike a balance between cutting the debt and continuing to invest in promising markets, particularly Latin America, to offset slow growth in Italy and Spain.

The government's candidate as chairwoman is Patrizia Grieco, who will replace Paolo Andrea Colombo.

The government named Francesco Caio as new chief of Italy's postal service, Poste Italiane SpA, which is entirely controlled by the state, replacing Massimo Sarmi, who has turned the company around since taking the helm in 2002. He more than doubled the postal service's revenue to EUR26 billion ($35.9 billion) from 2002 to 2013, by aggressively pushing financial services.

The government plans to sell up to a 40% stake later this year, hoping to raise as much as EUR5 billion in one of the biggest Italian privatizations in years.

Mr. Renzi appointed Mauro Moretti as new chief of Finmeccanica, replacing Alessandro Pansa. Mr. Moretti must continue the deep ongoing restructuring at Finmeccanica, aimed at focusing more tightly on defense and aerospace and paying down some EUR3 billion in debt.

Poste and Finmeccanica had no comments to make on the nominations.

Not all approve of the new government's decision to make such radical board changes.

"I don't agree with the principle of wiping the slate clean at all the companies: Some executives needed to go while others could have stayed," said Marco Giorgino, professor at the MIP Polytechnic of Milan. "The policy of starting from scratch isn't necessarily the wisest."

Manuela Mesco and Gilles Castonguay contributed to this article.

Write to Liam Moloney at liam.moloney@wsj.com

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