By Will Connors 

RIO DE JANEIRO--Brazilian authorities on Wednesday accused Italian oil company Saipem of being involved in a corruption scheme involving Brazil's state-run oil company, Petróleo Brasileiro SA, the latest international firm to be implicated in the wide-ranging scandal.

Brazilian federal prosecutors accused former Petrobras services director Renato Duque, who was arrested earlier this year for allegedly taking part in the scheme and is currently in prison, of accepting bribes from João Bernardi, a sales representative for Saipem in Brazil.

Both men were charged with money laundering and corruption on Wednesday.

Prosecutors said Wednesday that in exchange for Saipem winning contracts with Petrobras, Mr. Bernardi and colleagues paid $1 million in bribes to Mr. Duque through Swiss bank accounts, and gave him 13 works of art worth roughly $174,000.

At one point, prosecutors said, Mr. Bernardi was robbed in downtown Rio de Janeiro as he carried 100,000 Brazilian reais (about $30,000) in cash to give to Mr. Duque.

An attorney for Mr. Bernardi couldn't be located.

A spokeswoman for Saipem said the company has yet to be contacted by Brazilian authorities and would cooperate fully if it does.

Saipem, which is 43%-owned by Italian oil-and-gas giant Eni Spa, is also embroiled in a corruption scandal in Algeria. Italian magistrates contend that Saipem paid kickbacks to secure more than EUR8 billion (about $8.8 billion) in contracts in the North African country. The magistrates are seeking to indict several former top managers, including former Eni Chief Executive Paolo Scaroni.

Through a spokesman in February, Mr. Scaroni has denied any wrongdoing. Eni has, in the past, maintained it has no control over Saipem, despite its large stake.

Saipem isn't the first international firm implicated in the Petrobras scandal. Brazilian prosecutors say the shipbuilding arm of South Korean conglomerate Samsung paid bribes to a former executive at Petrobras, and have also accused Swedish builder Skanska AB of taking part in the corruption at Petrobras.

Samsung and Skanska officials didn't immediately respond to a request for comment. Previously, Skanska has said it has a zero tolerance against corruption and takes the situation seriously. Last July, Skanska announced it would shut down its Latin America operations.

Brazilian investigators allege some of Brazil's largest construction firms formed a cartel to drive up prices of Petrobras contracts and kicked back some of the windfall to Brazilian politicians, top political parties and corrupt executives at the oil firm.

Some have admitted wrongdoing in exchange for lesser punishment, prosecutors say, while others have denied involvement and await trial. Petrobras says it is a victim of the alleged scheme and is cooperating with authorities.

Eric Sylvers in Milan contributed to this article.

Write to Will Connors at william.connors@wsj.com

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